Bsc sem 5 chemistry book PDF : We are discussion about saurashtra university rajkot ty bsc sem 5 final 3rd year chemistry c 501 c 502 c 503 book pdf download.
Gujarati Education website provide you bsc semester 5 chemistry paper c 501,c 502, c 503 textbook free pdf download. Inorganic Chemistry and industrial chemistry, organic chemistry and spectroscopy, Physical chemistry and analytical chemistry books.
Bsc Semester 5 Chemistry Books PDF Download
Chemistry 501 : Inorganic Chemistry
and industrial chemistry
Unit - I
Chapter 1 : Wave Mechanics
Unit - II
Chapter 2 : Crystal Field Theory-1
Unit - III
Chapter 3 : Transition Metal Complexes of Acid Ligands
Ø Introduction
Ø Preparation of Metal Carbonyl
Ø Physical Properties
Ø Chemical Propertics
Ø Molecular Orbital Diagram of Co Molecule
Ø Nature of Linear M Cobond
Ø Physical Evidences for Multiple Nature of M-Co Bond
Ø Classification
Ø Types of Co Group in Metal Carbony
Ø Usefulness of Infra Red Spectra in The Study of Metal Carbonyl
Ø Structure of Some Metal Carbonyls
Ø Metal Nitrosyls
Chapter 4 : Cement
Ø Introduction
Ø Types of Cement
Ø Raw Materials for the Manufacture of Portland.Cement
Ø Functions of the Ingredients of Cement
Ø Cement Rock Beneficiation
Ø Manufacture of Portland Cement
Ø Setting and Hardening of Portland Cement
Ø Properties of Cement
Ø Indian Standards Institute (ISD Specification of Cement
Ø Mortars and Concrete
Ø Uses of Cement
Unit - IV
Chapter 5 : Fertilizer
Ø Introduction
Ø Plant Nutrients
Ø Nutrient Functions
Ø Need for Fertilisers
Ø Essential Requirements of Fertiliser
Ø Classification of Fertilisers
Ø Synthetic or Artificial Fertilisers
Unit - V
Chapter 6 : Glass
Ø Introduction
Ø Properties of Glass
Ø Raw Materials used for Manufacture of Glass
Ø Chemical Reactions Involved
Ø Manufacture of Glass
Ø Special Types of Glasses
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Chemistry 502 : Organic Chemistry
and Spectroscopy
Unit - I
Chapter 1 : Name Reactions, Re-arrangement & Reagents
Ø Reaction - 1 : Arndt-Eisterd synthesis
Ø Reaction - 2: Bischler-Napieralski Reaction
Ø Reaction - 3 : Wolff-Kishner Reaction
Ø Re-arrangement -1: Beckmann Re-arrangement
Ø Re-arrangement -2: Curtius Re-arrangement
Ø Re-arrangement 3: Baeyer-Villiger Oxidation
Ø Reagent - 1: Lithium Aluminum Hydride (LiAIH4)
Ø Reagent - 2: Triphenyl Phosphine [(C6H5)3P]
Ø Reagent - 3 : Sodamide (NaNH2)
Chapter 2 : Alkaloids
Ø Introduction
Ø Occurance
Ø Classification
Ø Isolation of alkaloids
Ø General method for proving structure of alkaloids
Ø Properties, Constitution and synthesis of Coniine
Ø Properties, Constitution and synthesis of Nicotine
Ø Properties, Constitution and synthesis of Papaverine
Unit - II
Chapter 3 : Carbohydrates
Ø Introduction
Ø Classification & Nomenclature
Ø Different types of Notations for representing mono-sachharides
Ø General reactions of mono-sachharides
Ø Inter-conversions of Saccharides
Ø Step-up Reactions (Ascending in Aldose series)
Ø Step-down, reactions (Desending in Aldose series)
Ø Configuration of mono-sachharides
Ø Ring structure of Aldose
Ø Determination of ring size of Glucose
Ø Mutarotation of D(+)-Glucose
Chapter 4 : Synthetic Drugs, Dyes & Sweetening Agents
v Synthetic Drugs :
Ø Ibuprofen
Ø Atenolol
Ø Adrenaline (Epinephrine)
v Synthetic Dyes :
Ø Orange-II (B-Naphthol orange)
Ø Crysodine-G (2,4-Diamino-azobenzene)
Ø Aurramine-O
v Sweetening agents :
Ø Saccharin (Cyclic amide of o-sulpho-benzoic acid) p-Anisylurea
Ø Dulcin (p-phen-ethyl-urea)
Unit - III
Chapter 5 : Synthesis of Heterocyclic Compound
Ø Introduction
Ø Pyrazole
Ø Imidazole
Ø Isoxazole
Ø Thiazole
Ø Pyrimidine
Ø Pyridazine
Ø Oxazine (Morpholine)
Ø Thiazine (Thio-morpholine)
Ø Dioxane
Chapter 6 : Ultraviolet and Visible Spectra
Ø Introduction
Ø Ultraviolet - Visible Spectrometer
Ø Type of transition
Ø Chromophore and Auxochrome
Ø Types of shift
Ø Factor affecting the position of absorption bands
Ø General application of UV-Visible spectra
Ø Calculation of Lmax
Chapter 7 : Symmetry
Ø Introduction
Ø Symmetry Elements & Symmetry Operations
Ø Some Important Operation which give Identity
Ø Laws of Symmetry
Ø Symmetry Point group
Ø Group Multiplication Table
Ø "VSEPER" Theory & Shape of Molecules
Unit - V
Chapter 8 : Infrared Spectroscopy
Ø Introduction of Infrared Spectroscopy
Ø Theory of IR-Spectroscopy
Ø Modes of fundamental vibration
Ø Infrared Activity
Ø Coupling of rotational and vibrations
Ø Selection rule for Infrared
Ø Type of IR-Band
Ø Finger Print region
Ø Instrumentation
Ø Factor affecting IR absorption
Ø Application of IR
[Determination of Structure of Organic Molecules(OM) From IR]
Ø Interpretation of IR for Given Molecules
Ø Problems based on IR-Spectroscopy
Ø Distinguish the following compound By IR-spectra
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Chemistry 503 : Physical Chemistry and Analytical Chemistry
v Physical Chemistry
Unit- I
Chapter 1 : Second law of Thermodynamics
Ø Introduction
Ø Limitations of First Law of Thermodynamics
Ø Spontaneous process
Ø Statement of Second Law of Thermodynamics
Ø Perpetual motion of the second kind
Ø Carnot Cycle and Theorem
Ø Concept of entropy, Definition of entropy
Ø Entropy change (∆S) in Reversible process
Ø Entropy change (∆S) in Irreversible (spontaneous) process
Ø Entropy change in an Ideal gas
Ø Entropy change in Misture of Ideal gas
Ø Entropy change (AS) in Physical Transformations
Ø Physical significance of entropy
Ø Entropy and Second Law of Thermodynamics
Ø Examples based on theory
Unit - II
Chapter 1 : Electrochemistry-1
Ø Introduciton
Ø Types of cell
Ø Half cell, standard half cell, standard cell
Ø Standard electrode potential
Ø Conventional sign and Representation of cell
Ø emf series
Ø Types of electrode such as Active, Innert and Gas electrode
Ø Types of reversible electrode
Ø Galvanic cell
Ø Hyderogen electrode, Calomel electrode, Glass electrode
Ø Reversible cell and Irreversible cell
Ø Nernst equation for the calculation of single. electrode. potential
Ø Examples based on theory
Chapter 2 : Phase Rule
Ø Introduction
Ø Definitions of terms related to Phase Rule
Ø Method of graphical presentation for three component system
Ø Types of partially miscible three liquid systems
Ø One pair of partially miscible liquids
Ø Two pair of partially miscible liquids
Ø Three pair of partially miscible liquids
Ø Application of ternary liquid phase diagram
Unit - III
Chapter 1 : Free energy and Chemical Equilibrium
Ø Introduction
Ø Work function (A)
Ø Physical significance of Work function
Ø Helmholtz equation (Relation of A with T and V)
Ø Gibbs Free Energy function (G)
Ø Physical significance of Gibb's free energy
Ø Gibbs Helmholtz equation (Relation of G with P and T)
Ø Method to determine change of free energy
Ø Free energy change (4G) for an Ideal gas
Ø Applications of Gibbs Helmholtz equation
Ø Criteria for Chemical Equilibrium
Ø Vant Hoff Isotherm reaction
Ø Clausitus Clapeyron equation
Ø Integration of Clausius Clapeyron equation
Ø Effect of pressure on meltingpoint of Ice
Ø Law of active massin reference of thermodynamics
Ø Law of mass in reference of Chemical Potential
Ø Examples based on theory
v Analytical Chemistry
Chapter 2 : Colourimetry
Ø Introduction
Ø Difference between Thermal & Photochemical Reaction
Ø Grothuss Draper Law
Ø Lambent's & Beer's law & Deviation
Ø Spectrophotometric titration
Ø Deficiat of absorbance
By product and titrant
By product and reagent
By reagent and titrant
By product only
Unit - IV
Chapter 1 : Conductometry
Ø Introduction : Electric transport
Ø Specific conductance, equivalent conductance
Ø Importance of Conductivity electrode
Ø Polarization of electrodes
Ø Efect on conduction on dilution and cross section area
Ø Kohlrausch law
Ø Conductometric titration
(i) Strong acid --> strong base
(ii) Strong acid --> weal base
(iii) Weak acid --> strong base
(iv) Mix of strong acid + weak acid --> strong base
Ø Precipitation Titration
Ø Replacement Titration
Ø Solubility, solubility product and sparingly soluble salt
Ø Degree of hydrolysis and Hydrolysis constant
Chapter 2 : Introduction of Complexometry Ttitation
Ø Introduction
Ø Method of Preparation of standard EDTA solution
Ø Velcher's Law
Ø Explanation of Pm --> EDTA
Ø Type of EDTA titration
Ø Masing and demashing agent
Ø Principle of metal ion indicator
Ø EBT, Calcon, Muroxide etc. structure and use
Unit - V
Chapter 1 : Volumetric Analysis
Ø Introduction
Ø Titration : Back titration, Endpoint, Bquivalence point
Ø Ostwald's Indicator Principle
Ø Derivation of Indicator
Ø Primary and secondary standard solution
Ø Characteristics of the standard substance
Ø Difference between End point and Equivalence point
Ø Explanation of neutralization titration with graph
(i) Strong acid --> Strong base
(ii) Weak acid --> Strong base
(iii) Strong acid --> Weak base
(iv) Poly protic acid --> Strong base
Ø Redox Titration
Ø Principle External and internal indicator
Ø Redox titration with graph and calculation
Ø Iodometry and Iodimetry titration
Ø Preparation of standard sodium thiosulphate solution
Ø Precipitation titration
(i) Mohr's method
(ii) Fezan's methos
(iii) Volhard's method
Ø Exmple based on: pH, Normality, Molarity Ksp ete.
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