Bsc sem 6 chemistry book PDF Download | final year | paper c- 601 | paper c- 602 | paper c- 603 | Saurashtra University | Gujarati Education

Bsc sem 6 chemistry book PDF : We are discussion about saurashtra university rajkot ty bsc sem 6 final 3rd year chemistry c 601 c 602 c 603 book pdf download.


          Gujarati Education website provide you bsc semester 6 chemistry paper c 601,c 602, c 603 textbook free pdf download. Inorganic Chemistry and industrial chemistry, organic chemistry and spectroscopy, Physical chemistry and analytical chemistry books.

Bsc Semester 6 Chemistry Books PDF Download

Chemistry 601 : Inorganic chemistry and Industrial Chemistry

Unit-I

1. Multi Electron System

Ø  Introduction to Multielectron System

Ø  Concept of spectral terms and term symbols

Ø  s-s coupling, l-l coupling, l-s coupling, j-j coupling and L-S coupling with vector diagram

Ø  Derivation of spectral term symbols for P1, P2, P3

Ø  Hund's Rules for the determination of Ground State Term Symbol

Ø  Derivation of microstates 


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Unit-II

2. Crystal Field Theory-II

Ø  Jahn Teller Effect

Ø  Tetragonal distortion with examples

Ø  Splitting of d-orbitals in square planar complexes

Ø  Hole Formalism and splitting of ‘D' and 'F' term

Ø  Orgel Diagram of 'D' and 'F' state

Ø  Relaxation of Selection Rule

Ø  Types of Electronic Transition in Metal Complexes

Ø  Absorption spectrum of Ti+3 , Cu+2 and Ni+2


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Unit-III

1. Magneto Chemistry

Ø  Introduction

Ø  Magnetic Induction

Ø  Magnetic behavious of a substance

Ø  Effect of temperature on magnetic behaviour of substance

Ø  Derivation of equation for total angular magnetic momentum and diamagnetic momentum

Ø  Determination of Magnetic Susceptibility by Gouy's Method 


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2. Oils and Fats

Ø  Introduction

Ø  Distinction between Oil seed & Fats and their classification

Ø  Properties oil & fats

Ø  Manufacturing of cotton seed oil by expression method and solvent extraction method

Ø  Refining of crude vegetable oil

Ø  Analysis of Oils and Fats :

             (i) Saponification Value

             (ii) Acid value

             (iii) Iodine Value

             (iv) Reichert-Meissl Value ( M. R. Value) 

 

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Unit-IV

1. Environmental Pollution

Ø  Environment : Definition and Introduction

Ø  Segment of environment

Ø  Air Pollution:

            a. Introduction 
            b. Green House Effect 
            c. Major sources of air pollution
            d. Photochemical smog and acid rain 
            e. CFC and ozone depletion 
            f. Source and effect of NOx and SOx
            g. Control of air pollution

Ø  Introduction and classification of Water Pollution

         (a) Types of of water pollution 

                 i. Physical pollution 
                ii. Chemical pollution
               iii.Biological pollution 
               iv. Physiological pollution

         (b) Source of water pollution :

                i. Sewage and domestic waste
               ii. Industrial effluents
              iii. Agricultural discharge
              iv. Fertilizers
               v. Toxic metals 
              vi. Siltation 
             vii. Thermal pollution
            viii. Radio active materials

Ø  Water pollution control

Ø  Dissolved oxygen (D.O.) determination

Ø  Chemical oxygen demand (C.O.D.) determination

Ø  Biological oxygen demand (B.O.D.) determination 


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Unit-V

1. Soaps and Detergents

Ø  Introduction to soap

Ø  Manufacture of soap

Ø  Recovery of glycerine from spent lye

Ø  Introduction to Detergents

Ø  Principle group of Synthetic Detergents

Ø  Biodegradability of Surfactants

Ø  Classification of Surface Active Agents

Ø  Anionic Detergents : (Manufacture of Anionic detergents)

Ø  Cationic Detergents

Ø  Non Ionic detergents: Batch process

Ø  Ampholytic Surfactant

Ø  Manufacture of Shampoo

Ø  Comparison of Soaps and Detergents


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Chemistry 602 : Organic Chemistry and Spectroscopy

Unit-I

1. Terpenoids 

Ø  Introduction

Ø  Occurrence

Ø  Isolation 

Ø  Classification of Terpenoids 

Ø  Physical Propertiesof Terpenotds 

Ø  Chemical Properties of Terpenoids 

Ø  Determining the Structure of Terpenoids 

Ø  CITRAL or (3,7-dimethyl-2,6-diene octanal)

Ø  Synthesis of Citral or synthesis of 3, 7-dimethyl: 2, 6-diene octanal 

Ø  Constitution of a-Terpineol

Ø  Synthesis of a-Terpineol (Jr. Perkin and Co-workers) 


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2. Synthetic Explosives, Perfumes and Insecticides

Ø  Synthesis and uses of : Explosives 

                   (a) RDX or  CYCLONITE 

                   (b) T.N.T. (Tri Nitro Toluene) 

                   (c) P.E.T.N. (Penta Erythritol Tetra Nitrate)

Ø  Synthesis and uses of : Perfumes

                    (a) Musk Xylene 

                    (b) Musk Ketone 

                    (c) Musk Ambrette 

Ø  Synthesis and uses of : Insecticides 

                   (a) Baygon

                   (b) Carbendazin

                   (c) Parathion 

 

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Unit-II

1. Amino acids, Peptides and Proteins

Ø  Introduction 

Ø  Structure of Amino acids

Ø  Classification of Amino acids

Ø  Origin of the single-letter code for the amino acids

Ø  Synthesis of Amino-acids 

Ø  Physical Properties of Amino acids 

Ø  Chemical Properties of Amino acids

Ø  Isoelectric point Zwitterion 

Ø  Introduction to Polypeptides 

Ø  Synthesis of polypeptides by following methods

Ø  Introduction and classification of Proteins

Ø  Constitution of Thyroxn 

Ø  Synthesis of Thyroxin 

 

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Unit-III

1. Polynuclear Aromatic Hydrocarbons

Ø  Introduction

Ø  Classification of Polynuclear hydrocarbon

Ø  Synthesis and chemical properties 

Ø  Synthesis and chemical properties of Diphenyl methane synthesis of Diphenyl

Ø  Synthesis and Chemical properties of Naphthalene synthesis of Naphthalene

Ø  Synthesis and Chemical properties of Anthracene 

 

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2. Conformational Isomerism

Ø  Introduction. 

Ø  Conformational Analysis of Cyelohesane : Boat form and Chair form 

Ø  Conformation of Mono-substituted Cyclohexane

Ø  Conformation analysis of 1-2-Disubstituted Cyclohexane

Ø  Conformation analysis of 1,3-Disubstituted cyclohexane 

Ø  Conformation analysis of 1,4-Disubstituted cyclohexane 

 

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3. Mass Spectroscopy

Ø  Introduction

Ø  Principle of Mass Spectroscopy 

Ø  Mass Instrumentation 

Ø  Fragmentation Modes

Ø  Important features for the mass spectra of alkanes

Ø  McLafferty Rearrangement 

Ø  Mass Spectra of Alkanes 

 

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Unit-IV

1. Nuclear Magnetic Resonance Spectroscopy (NMR Spectroscopy)

Ø  Introduction

Ø  Principle of NMR spectroscopy 

Ø  Nuclear quantum number 

Ø  Flipping of the proton 

Ø  Instrumentation 

Ø  Equivalent and Non-equivalent protons

Ø  Enantiomeric and Diastereomeric Protons

Ø  Shielding and deshielding of protons

Ø  Chemical Shift 

Ø  Causes of Chemical Shift (factor affecting on chemical shift)

Ø  Relative Intensity of Signals 

Ø  Spin-spin Coupling

Ø  Spin-spin Coupling Constant

Ø  Paramagnetie Anisotropic effect

Ø  Deuterium labelling 

 

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Unit-V

1. Problems based on UV, IR, NMR Spectroscopy

Ø  Problems based on UV Spectroscopy

Ø  Problems based on IR Spectroscopy

Ø  Problems based on NMR Spectroscopy 

 

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Chemistry 603 : Physical Chemistry and Analytical Chemistry

UNIT-I 

1. Activity of Electrolytes

Ø  Introduction : Ionic Activity 

Ø  Activity co-efficient, mean activity, mean activity co-efficient

Ø  Relation of activity & activity co-efficient 

Ø  Derivation of activity & activity co-efficient 

Ø  Ionic strength 

Ø  Debye-Huckel limiting law 

Ø  Empirical correction for Debye-Huckel limiting law

Ø  Methods to determine activity co-efficient 

-          Solubility method 

-          EMF method 

Ø  Examples 

 

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2. Third Law of Thermodynamics

Ø  Introduction

Ø  Statements of Scientist for Third Law of Thermodynamics 

Ø  Mathematical form of the Third Law of Thermodynamics 

Ø  Nernst heat theorem

Ø  Determination of absolute entropies of solid, liquid & gas

Ø  Test of Third Law of Thermodynamics 

Ø  Application of Third Law of Thermodynamics ( ∆S°, ∆G° and K of chemical reaction) 

Ø  Residual entropy 

 

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UNIT-II

1. Electrochemistry-2 

Ø  Introduction (With useful terms) 

Ø  Electro chemical cell and concentration cell 

Ø  Liquid Junction Potential (LJP) 

Ø  Elimination of Liquid Junction Potential (LJP) 

Ø  Electrolyte concentration cell 

Ø  Application of emf measurement 

Ø  Determination of 

-          Solubility product and solubility of sparingly soluble. salt 

-          Valency for metal ion

-          Dissociation constant of weak acid

-          Transport no. of ion 

-          ionic product of water 

-          Degree of hydrolysis of salt 

-          pH for solution by different electrode

 

Ø  Information table for standard oxidation potential

Ø  Examples 

 

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UNIT-III

1. Partial Molar Properties 

Ø  Introduction 

Ø  Partial molar properties

Ø  Concept of chemical potential

Ø  Gibbs-Duhem equation 

Ø  Variation of chemical potential with temperature and pressure 

Ø  Determination of partial. molar. properties by method of intercept 

Ø  Application of chemical potential

-          Henry’s law 

-          Nernst's distribution law 

-          Raoult's law 

 

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2. . Error and Statistics 

Ø  Introduction 

Ø  Explanation of errors and mistakes 

Ø  Classification of Errors

Ø  Methods for Minimization of Errors 

Ø  Accuracy precision and difference between them

Ø  What is significant figures ?

Ø  Explain the following terms

Ø  Gausian curve and its explanation 

Ø  Importance of Q-test and T-test 

 

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UNIT-IV

1. Chromatography 

Ø  Introduction 

Ø  Classification of chromatography and types 

Ø  Terminologies used in chromatography 

Ø  Adsorption chromatography : Column chromatography

Ø  Partition Chromatograph (Paper & TLC) 

Ø  Thin Layer chromatography 

Ø  Gas chromatography 

Ø  Jon Exchange Chromatography 

 

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UNIT-V 

1. Basic Principle of Qualitative Analysis

Ø  Separation of Cl-, Br- and I-

Ø  Separation of NO2-, NO3- , Br-

Ø  Separation of S -2, SO3 -2, SO4 -2

Ø  Separation of PO4 -3, AsO4 -3, AsO3 -3

Ø  Separation of CO3 -2, SO3 -2, S -2

Ø  Separation of Cu +2 and Cd +2

 

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2. Potentiometry and pH metry 

Ø  Introduction

Ø  Types of potentiometry titration

Ø  Redox titration 

Ø  Argentometric titration 

Ø  Examples 

 

pH Metry

Ø  pH 

Ø  Methods for measurement of pH

Ø  Acid-Base titration by pH metry 

Ø  Determination of dissociation constant of weakacid by pH metry

Ø  Examples 

 

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Bsc sem 5 chemistry book 


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